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1,4-benzenedicarboxylic acid : ウィキペディア英語版
Terephthalic acid

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Terephthalic acid is the organic compound with formula C6H4(CO2H)2. This white solid is a commodity chemical, used principally as a precursor to the polyester PET, used to make clothing and plastic bottles. Several million tonnes are produced annually.〔
==History==
The importance of the terephthalic acid was realized after World War II. The first companies to commercialize the use of the fibers made from polyethylene terephthalate were Imperial Chemical Industries in the UK in 1949 and DuPont in the US in 1953. The fibers were made from dimethyl terephthalate by transesterification with ethylene glycol. Terephthalic acid was produced by oxidation of ''p''-xylene with dilute nitric acid. This type of oxidation involved the use of air in the initial oxidation step to minimize the consumption of nitric acid and difficulty in purification. Growth in the textile industry led to increase in demand of TPA. In the 1960s, all the terephthalic acid produced was converted to its dimethyl ester, since TPA and was infusible and difficult to purify. Presently TPA is manufactured by oxidation of ''p''-xylene.

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